Main Article Content

Abstract

Acid mine drainage for Fe and Mn metals have a negative impact on the environment. This study studies the use of calcium oxide and fly ash as adsorbents, used to absorb Fe and Mn metals contained in acid mine drainage. This study aims to analyze the effectiveness of Calcium Oxide and fly ash as adsorbents, that an adsorbent of Fe and Mn metals in acid mine drainage. The method used is experimental with a laboratory scale, the test is carried out by adsorption using a batch system. Magnetic stirrer is used as a stirring medium in the adsorption process. Calcium oxide with various doses (0.1; 0.2; 0.3 grams) and fly ash with various doses (10; 14; 17 grams) were mixed with 250 ml acid mine drainage, then stirred at a speed of 150 rpm and (30; 60; 90 minutes) stirring time. The characterization of the adsorbent was carried out by SEM testing. The results show that fly ash adsorbent has a better adsorption effectiveness than calcium oxide. The effectiveness of Fe is 85.35% and Mn 78.14%. While calcium oxide has the effectiveness of Fe 72.91% and Mn 61.81%. SEM testing of holes that increase and enlarge after adsorption, as well as the filling of the cavity by the material indicates the success of the adsorption process.

Keywords

adsorption calcium oxide effectiveness fly ash SEM

Article Details

How to Cite
Pratama, H., Nursanto, E., Ernawati, R., & Giatman, M. (2022). Adsorption of Heavy Metals Fe and Mn in Acid Mine Drainage from Coal Mining Waste Using Calcium Oxide and Fly Ash. INVOTEK: Jurnal Inovasi Vokasional Dan Teknologi, 22(2), 107-116. https://doi.org/https://doi.org/10.24036/invotek.v22i2.1020

References

  1. R. S. Gautama, Pembentukan, Pengendalian dan Pengelolaan Air Asam Tambang, II. Bandung: ITB Press, 2019.
  2. M. S. Abfertiawan, “Model Transpor Air Asam Tambang Melalui Pendekatan Daerah Tangkapan Air,” Institut Teknologi Bandung, 2016.
  3. J. Collie dan S. Stephen, Literature in The Languange Classroom: A Resource book of Ideas and Activity. Cambridge University Press, 2008.
  4. I. T. N. Siregar, “Analisis Netralisasi Air Asam Tambang Menggunakan CaO dan Fly Ash Pada PT. Alamjaya Bara Pratama Kabupaten Kutai Kartanegara, Provinsi Kalimantan Timur,” Universitas Pembangunan Nasional “Veteran” Yogyakarta, 2019.
  5. A. P. Gobel, E. Nursanto, dan W. D. Ratminah, “Efektifitas Pemanfaatan Fly Ash Batubara Sebagai Adsorben Dalam Menetralisir Air Asam Tambang pada Settling Pond Penambangan Banko PT. Bukit Asam (Persero), Tbk,” J. Miner. Energi dan Lingkung., vol. 2, no. 1, hal. 1–11, 2018, doi: 10.31315/jmel.v2i1.2113.
  6. B. Arifin, “Penggunaan Abu Batu Bara PLTU MPANAU Sebagai Bahan Stabilisasi Tanah Lempung,” SMARTek, vol. 7, no. 4, hal. 219–228, 2009.
  7. Z. T. Yao et al., “A comprehensive review on the applications of coal fl yash,” Earth-Science Rev., vol. 141, hal. 105–121, 2015, [Daring]. Tersedia pada: http://linkinghub.elsevier.com/retrieve/pii/S0012825214002219.
  8. S. J. Kulkarni, S. R. Dhokpande, dan J. P. Kaware, “Studies On Flyash As An Adsorbent For Removal Of Various Pollutants From Wastewater,” Int. J. Eng. Res. Technol., vol. 2, no. 5, hal. 1190–1195, 2013, [Daring]. Tersedia pada: https://www.ijert.org/research/studies-on-flyash-as-an-adsorbent-for-removal-of-various-pollutants-from-wastewater-IJERTV2IS50668.pdf.
  9. E. R. Aida, S. Y. Lisha, dan Y. Puty, “Pemanfaatan Limbah Abu Terbang Batubara (Fly Ash) Di Pltu Ombilin Sebagai Bahan Koagulan,” J. Pendidik. Teknol. Kejuru., vol. 1, no. 3, hal. 125–131, 2018, doi: 10.24036/jptk.v1i3.2223.
  10. Peraturan Pemerintah Republik Indonesia, “Peraturan Pemerintah Republik Indonesia Nomor 22 Tahun 2021 tentang Penyelenggaraan Perlindungan dan Pengelolaan Lingkungan Hidup.” 2021.
  11. M. A. Hossain, H. H. Ngo, W. S. Guo, dan T. V. Nguyen, “Removal of copper from water by adsorption onto banana peel as bioadsorbent,” Int. J. GEOMATE, vol. 2, no. 2, hal. 227–234, 2012, doi: 10.21660/2012.4.3c.
  12. C. Nwodika dan O. D. Onukwuli, “Adsorption Study of Kinetics and Equilibrium of Basic Dye on Kola Nut Pod Carbon,” Gazi Univ. J. Sci., vol. 30, no. 4, hal. 86–102, 2017.
  13. R. Delaroza, “Adsorpsi logam berat menggunakan adsorben alami pada air limbah industri,” Universitas Trisakti Jakarta, 2018.
  14. Badan Standardisasi Nasional, “SNI 6989.59:2008 Metoda Pengambilan Contoh Air Limbah.” 2008.
  15. Badan Standardisasi Nasional, “SNI 6989.4:2009 Cara Uji Besi (Fe) Secara Spektrofotometri Serapan Atom (SSA).” 2009.
  16. Badan Standardisasi Nasional, “SNI 6989.5:2009 Cara Uji Mangan (Mn) Secara Spektrofotometri Serapan Atom (SSA).” 2009.
  17. Keputusan Menteri Negara Lingkungan Hidup, “Keputusan Menteri Negara Lingkungan Hidup Nomor 113 Tahun 2003 tentang Baku Mutu Air Limbah Bagi Usaha dan atau Kegiatan Pertambangan Batubara.” 2003.
  18. M. Paradise, “Adsorpsi Logam Berat Besi (Fe) dan Mangan (Mn) Menggunakan Komposit Claystone, Zeolit, dan Arang Aktif Tempurung Kelapa pada Sampel Air Asam Tambang Batubara,” Universitas Pembangunan Nasional “Veteran” Yogyakarta, 2021.
  19. W. Stumm dan J. J. Morgan, Aquatic chemistry: chemical equilibria and rates in natural waters, 126 ed. John Wiley & Sons, 2012.